catena-Poly[[dichloridozinc(II)]-μ-1,1′-(butane-1,4-diyl)diimidazole-κ2 N 3:N 3′]
نویسندگان
چکیده
The title compound, [ZnCl(2)(C(10)H(14)N(4))](n), is a coordination polymer consisting of zigzag chains propagating in [001], in which the metal cation exhibits a distorted tetrahedral ZnCl(2)N(2) coordination. Adjacent chains are linked by inter-molecular C-H⋯Cl hydrogen bonds, forming a three-dimensional supra-molecular network.
منابع مشابه
catena-Poly[[dichloridozinc(II)]-μ-[1,1′-(butane-1,4-diyl)diimidazole-κ2 N 3:N 3′]]
The title one-dimensional coordination polymer, [ZnCl(2)(C(10)H(14)N(4))](n), was synthesized by hydro-thermal methods from ZnCl(2) and 1,1'-(butane-1,4-di-yl)diimidazole. The Zn atom is coordinated by two chloride ions and two N atoms from two symmetry-independent organic ligands and shows a distorted tetra-hedral coordination geometry. The 1,1'-(butane-1,4-di-yl)diimidazole ligands are locate...
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In the title compound, {[Cu(C(10)H(14)N(4))(2)(H(2)O)(2)](NO(3))(2)}(n), the Cu(II) ion lies on an inversion center and is six-coordinated in an octa-hedral environment by four N atoms from four different 1,1'-butane-1,4-diyldiimidazole ligands and two O atoms from the two water mol-ecules. Bridging by the ligands results in a ribbon structure. Adjacent ribbons are linked to the nitrate anions ...
متن کاملPoly[[[μ-1,1′-(butane-1,4-diyl)diimidazole-κ2 N 3:N 3′](μ-cyclohexane-1,4-dicarboxylato-κ4 O 1,O 1′:O 4,O 4′)nickel(II)] 0.25-hydrate]
In the title coordination polymer, {[Ni(C(8)H(10)O(4))(C(10)H(14)N(4))]·0.25H(2)O}(n), the coordination of the Ni(II) ion is distorted octa-hedral. The 1,1'-(butane-1,4-di-yl)diimidazole ligand and the cyclo-hexane-1,4-dicarboxyl-ate dianion bridge metal centres, forming a two-dimensional (4,4) network. The network is consolidated by O-H⋯O hydrogen bonds between the statistically occupied water...
متن کاملcatena-Poly[[dichloridozinc(II)]-μ-1,1′-(hexane-1,6-diyl)diimidazole-κ2 N 3:N 3′]
In the structure of the polymeric title compound, [ZnCl(2)(C(12)H(18)N(4))](n) or [ZnCl(2)(L)](n), where L = 1,1'-(hexane-1,6-di-yl)diimidazole, the Zn(II) centre is coordinated by two N atoms of two different L ligands and by two chloride anions in a distorted tetra-hedral geometry. The organic ligand links adjacent metals to form a polymeric chain along the c axis. The chains are further conn...
متن کاملPoly[[μ2-2,2′-diethyl-1,1′-(butane-1,4-diyl)diimidazole-κ2 N 3:N 3′](μ2-5-hydroxyisophthalato-κ2 O 1:O 3)zinc]
In the title coordination polymer, [Zn(C(8)H(4)O(5))(C(14)H(22)N(4))](n), the Zn(II) cation is coordinated by an O(2)N(2) donor set in a distorted tetra-hedral geometry. The Zn(II) ions are linked by μ(2)-OH-bdc (OH-H(2)bdc = 5-hy-droxy-isophthalic acid) and bbie ligands [bbie = 2,2'-diethyl-1,1'-(butane-1,4-di-yl)diimidazole], forming a two-dimensional layer parallel to the ab plane. The layer...
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